The Constitution of Nickel Carbonyl and the Nature of Secondary Valence (Classic Reprint)

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Excerpt from The Constitution of Nickel Carbonyl and the Nature of Secondary ValenceExperimental data concerning the reaction of nickel carbonyl with the non-metals bromine, sulfur, oxygen and with the Grignard reagent are given.The data support the claim that nickel carbonyl is a compound in which secondary valence alone is exerted, either constituent being free to enter into its ordinary reactions, the other constituent being thereby left alone in its ordinary free condition.A structure Of the extremely volatile carbonyls is proposed which would give a very small stray electrostatic field, the Sheath of the metal atom contains 18 electrons in each case.About the PublisherForgotten Books publishes hundreds of thousands of rare and classic books. Find more at www.forgottenbooks.comThis book is a reproduction of an important historical work. Forgotten Books uses state-of-the-art technology to digitally reconstruct the work, preserving the original format whilst repairing imperfections present in the aged copy. In rare cases, an imperfection in the original, such as a blemish or missing page, may be replicated in our edition. We do, however, repair the vast majority of imperfections successfully, any imperfections that remain are intentionally left to preserve the state of such historical works.