Phenyliminomalonates and the Mechanism of Their Reactions (Classic Reprint)

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Excerpt from Phenyliminomalonates and the Mechanism of Their ReactionsWe have studied methyl phenyliminomalonate condensations with the three toluidines, benzylamine, hydrocyanic and hydrochloric acids. With the ortho and para toluidines white crystalline addition products were formed, but with the meta a glycerol like oil was produced. With hydrocyanic acid a dark red oil was formed which we were unable to purify on account of its instability. The hydrochloric acid addition product is a white crystalline compound at -150, but rapidly decomposes with evolution of hydrochloric acid gas when exposed to the air at room temperature. Benzylamine gives a stable, white, crystalline product.About the PublisherForgotten Books publishes hundreds of thousands of rare and classic books. Find more at www.forgottenbooks.comThis book is a reproduction of an important historical work. Forgotten Books uses state-of-the-art technology to digitally reconstruct the work, preserving the original format whilst repairing imperfections present in the aged copy. In rare cases, an imperfection in the original, such as a blemish or missing page, may be replicated in our edition. We do, however, repair the vast majority of imperfections successfully, any imperfections that remain are intentionally left to preserve the state of such historical works.