Fast Pyrolysis of Technical Lignins in a Circulating Fluidized Bed Reactor

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In search of an alternative for chemicals and energy from fossil fuels, lignin pyrolysis is experimentally investigated in a circulating fluidized bed. Deviation in pyrolysis behavior of a softwood Kraft lignin and a wheat straw hydrolysis lignin is analyzed by means of char morphology as well as overall yield and composition determination for gas, oil, and char. The influence of catalytically active mineral matter in lignin on the product distribution is investigated. Progressively, the fluidized bed pyrolysis process is modeled semi-empirically considering fluid dynamics, feedstock composition, micro-particle pyrolysis reactions and mass balances. The lignin secondary reaction kinetics from oil-to-gas are obtained from the Kraft lignin experimental data and a pyrolysis plant with integrated char and permanent gas combustion is modeled with a flowsheeting tool.